Product ID:LA 6660 (F)
MSDS Date:01/05/1996
FSC:6850
NIIN:00N084147
MSDS Number: CGSHR

ASHLAND CHEMICAL INC

COLUMBUS, OH 43216
US

Emergency Phone: 800-274-5263

Info Phone: 614-790-3333

Cage: 34897

ASHLAND CHEMICAL CO

2219 COLUMBUS, OH 43216-2219 US

Telephone: 614-790-3333/800-274-5263

Cage: 34897

VM & P NAPHTHA; (ALIPHATIC PETROLEUM DISTILLATES)

CAS: 64742-89-8

Fraction By Weight: 35-39%

OSHA PEL N/K

ACGIH TLV: N/K

ACETONE (SARA 313) (CERCLA)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 20-24%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM/1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 18.4%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETIC ACID, ISOBUTYL ESTER; (ISOBUTYL ACETATE) (CERCLA)

CAS: 110-19-0

RTECS: AI4025000

Fraction By Weight: 8-12%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 66%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM/500 STEL

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 4%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM/250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 1-5%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

IRRIT (NOSE, THROAT, RESP TRACT), CNS

RTECS: 9999999ZZ

VISUAL IMPAIRMENT (INCL BLINDNESS), & DEATH. TARGET

RTECS: 9999999ZZ

BLOOD & LIVER

RTECS: 9999999ZZ

LUNG & BRAIN DMG. MAY CAUSE EYE DMG IN HUMANS.

RTECS: 9999999ZZ

STUDIES. INTENTIONAL MISUSE BY DELIB INHAL OF

RTECS: 9999999ZZ

RPTD EXPOS TO TOLUENE HAS CAUSED HIGH FREQUENCY

RTECS: 9999999ZZ

HLTH CONSEQUENCES OF THIS FINDING IS UNCERTAIN.

RTECS: 9999999ZZ

HARM TO FETUS OCCURS ONLY AT EXPOS LEVELS THAT HARM

RTECS: 9999999ZZ

HUMANS IS UNCERTAIN. TOLUENE APPEARS ON THE NAVY

RTECS: 9999999ZZ

PROFESSIONALS CONCERNING LATEST HAZ LIST INFO &

RTECS: 9999999ZZ

DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS,

RTECS: 9999999ZZ

OF 2-BUTOXYETHANOL (EXTRACTED FROM DHHS (NIOSH)

RTECS: 9999999ZZ

SEEK IMMED MED ATTN. KEEP WARM & QUIET. IF

RTECS: 9999999ZZ

CONTAINS METHANOL WHICH CAN

RTECS: 9999999ZZ

FORMIC ACID & FORMALDEHYDE. THESE METABOLITES CAN

RTECS: 9999999ZZ

SINCE METABOLISM IS REQUIRED FOR THESE TOX SYMPS,

RTECS: 9999999ZZ

ETHANOL COMPETES FOR SAME METABOLIC PATHWAY & HAS

RTECS: 9999999ZZ

IS INDICATED IN SYMP PATIENTS/AT BLOOD METHANOL

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: IRRIT, INCL STINGING,
TEARING, REDNESS, SWELL & DMG. SKIN: MAY CAUSE MILD IRRIT.
PRLNG/RPTD EXPOS MAY DRY SKIN, INCL REDNESS, BURNING, DRYING &
CRACKING, BURNS. SKIN ABSORPTION IS POSS, & MAY CONTRIBUTE TO
SYMPS OF TOXICITY FROM OTHER RTES OF EXPOS. INGEST: SINGLE DOSE
ORAL TOXICITY MOD. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MAY BE HARMFUL. CAN CENTER LUNGS
DURING SWALLOWING/VOMIT & CAUSE LUNG INFLAMM &/OR DMG. INHAL: EXPOS
TO VAP/MIST POSS. SHORT-TERM INHAL TOXICITY IS LOW. BRTHG SML AMTS
DURING NORM HNDLG IS N OT LIKELY TO CAUSE HARMFUL EFTS; BRTHG LGE
AMTS MAY BE HARMFUL. SYMPS OF EXPOS: GI IRRIT (NAUS, VOMIT, DIARR),
(ING 8)
Medical Cond Aggravated by Exposure:PREEXISTING BLOOD AND LIVER
ABNORMALITIES. NASAL, SPLEEN, TESTIS, NERVOUS SYSTEM, EYE, KIDNEY,
LUNG, AND BRAIN DAMAGE.

First Aid:EYE:IMMED MOVE TO FRESH AIR. FLUSH GENTLY W/WATER FOR AT
LEAST 15 MIN, HOLDING EYELIDS APART; SEEK IMMED MED ATTN.
SKIN:REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. WASH SKIN W/SOAP &
WATER. IF SYMPS P ERSIST, SEEK MED ATTN. INGEST:IMMED DRINK 2
GLASSES OF WATER & INDUCE VOMIT BY GIVING IPECAC SYRUP/BY PLACING
FINGER AT BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERS. GET MED (SUP DAT)

Flash Point Method:TCC
Flash Point:<-1F,<-18C
Lower Limits:1.1%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . REFER TO THE PERSONAL PROTECTIVE EQUIPMENT SECTION OF
THIS MSDS.
Unusual Fire/Explosion Hazard:HIGHLY VOLAT & READILY GIVES OFF VAPS
WHICH MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY PILOT
LIGHTS, OTHER FLAMES, SPKS, HEATERS, SMKNG, (SUP DAT)

Spill Release Procedures:SML SPILL:ABSORB ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LGE SPILL:ELIM ALL IGNIT SOURCES (FLARES,
FLAMES INCL PILOT LIGHTS, ELEC SPKS). WEAR PROT EQUIP. STOP SPILL
AT SOURCE. PVNT FROM ENTERI NG DRAINS, SEWERS. CONT NEHC FOR MORE
INFO .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTRS MAY BE HAZ WHEN EMPTIED. SINCE
EMPTIED CONTRS RETAIN PROD RESIDUE (VAP, LIQ &/OR SOLID), ALL HAZ
PREC GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:ALL 5 GAL PAILS & LARGER METAL CONTRS INCL TANK CARS
& TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN TRANSFERRED. USE
IN ELEVATED TEMP PROCESSES SHOULD BE THORO EVALUATED TO ESTABLISH &
MAINT SAFE C NDTNS. CONT NEHC FOR MORE INFO .

Respiratory Protection:IF EXPOS LIM IS EXCEEDED, NIOSH APPRVD AIR SUPP
RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO
PERMIT OTHER NIOSH APPRVD RESPS (NEG PRESS TYPE) UNDER SPECIFIED
CNDTNS. IMPLEMENT ENGI NEERING/ADMIN CONTROLS TO REDUCE EXPOS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WEAR IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:ELEC MOTORS, STATIC DISCHARGE/OTHER IGNIT SOURCES AT
LOCATIONS DISTANT FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING
TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE)
CAN I GNITE EXPLO. FIRST AID PROC:ATTN IMMED.(ASPIR INTO LUNGS CAN
CAUSE CHEM PNEUM). INHAL:IMMED MOVE TO FRESH AIR. (ING 20)

Boiling Pt:B.P. Text:133F,56C
Vapor Pres:181.7@68F
Spec Gravity:0.790 @ 77F
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:LIQUID (HOMOGENOUS SOLUTION)
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
MONOXIDE, VARIOUS HYDROCARBONS.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.